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Malachite Green C.I. Basic Green 4 - Premium Quality from China Suppliers & Factory, CAS 569-64-2
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Malachite Green C.I. Basic Green 4 - Premium Quality from China Suppliers & Factory, CAS 569-64-2

Introducing our high-quality Basic Malachite Green, also known as Crystal Malachite Green or Basic Brilliant Green. With a Color Index No. of 42000 and Basic Green 4, this product is a top choice among China suppliers and manufacturers, Our Basic Malachite Green features the CAS No. 569-64-2, and it has a precise molecular formula of C₂₃H₂₅ClN₂, resulting in a molecular weight of 329.4As part of the triphenylmethane basic/cationic dyes category, it is ideal for various applications, The product is available in green crystals or powder form, showcasing a striking metallic luster that enhances its appeal. Whether you are sourcing from a factory in China or looking for reliable suppliers, our Basic Malachite Green meets the highest quality standards for your needs

    Introduction

    Basic Dye Malachite Green, also known as Basic Green 4, belongs to triphenylmethane basic and cationic dyes.

    Basic Dye Malachite Green - Basic Green 4

    Main Characteristics

    Acid Reaction & Color Shifts

    It appears yellow in concentrated sulfuric acid and turns dark orange after dilution; it is orange in concentrated nitric acid and turns orange-brown after dilution.

    Solubility & Solution Appearance

    Soluble in water, highly soluble in ethanol, with a distinctive blue-green solution color.

    Alkali Precipitation

    When sodium hydroxide is added to its aqueous solution, a white precipitate with green fluorescence is formed.

    Thermal Stability & Fastness

    Stable shade at high temperature (120℃); light fastness reaches grade 4–5 on acrylic fiber.

    Legal Industrial Applications

    1. Textile Printing and Dyeing

    It has good tinting power on natural fibers such as cotton, linen and silk. The light fastness on acrylic fiber and diacetate fiber can reach grade 4–5. It can be blended with basic fuchsin to produce jet black shade.

    2. Biological Stain

    It is an important biological stain, which can stain cells or tissues blue-green for microscopic observation. It is applied in bacterial spore staining and colorimetric determination of serum phosphate concentration.

    3. Other Industrial Uses

    It is used for coloring paper, paints and inks, and also serves as an acid-base indicator (color changes from yellow to green at pH 0–2, and from green to colorless at pH 11–13.5). It is also applied in degradation research in the field of photocatalysis.

    Illegal Adulteration & Food Safety Risks

    Due to its ability to brighten the color of inferior food, Basic Malachite Green (Basic Green 4) is frequently abused by illegal vendors.
    Typical Illegal Use Cases:
    • Dyed kelp: Illegally soaked kelp to create a bright and fresh appearance.
    • Banned fishery drug: Used for fish disease treatment and fresh-keeping during transportation in aquaculture. Consumption of fish containing Malachite Green poses serious health risks. Its metabolite, Leucomalachite Green, has been linked to increased liver tumors in animal experiments.
    • Harm to aquatic products: It causes gill and skin inflammation in fish, affects enzyme secretion, and leaves long-term residues in organisms. It will endanger human health through the food chain.
    • Other foods: There have been historical reports of illegal dyeing of soft-shelled turtles and other aquatic products.

    Precautions

    • As an industrial dye, it is strictly prohibited for use in food, aquaculture and pharmaceutical purposes (once illegally used for coloring kelp and aquatic products).
    • Avoid dust inhalation, skin and eye contact during handling; proper personal protection is required.
    • Store in a cool, dry place with sealed packaging to prevent moisture.
    In short, Basic Green 4 (Basic Malachite Green) is a widely used industrial dye with high toxicity, and it is strictly prohibited from any contact with food. For industrial applications, proper safety protection must be ensured and relevant regulations shall be strictly followed.

    Frequently Asked Questions (FAQ)

    What is Basic Malachite Green (Basic Green 4)?
    Basic Malachite Green (also designated as Basic Green 4) is a synthetic cationic dye belonging to the triphenylmethane class, widely recognized for its intense blue-green coloration and strong tinting strength.
    What are the primary industrial applications of Basic Green 4?
    It is legally utilized in textile dyeing (acrylic, silk, cotton, and linen), biological tissue and spore staining in laboratory research, paper and ink manufacturing, acid-base pH indicators, and photocatalytic degradation testing.
    Why is Malachite Green strictly prohibited in food and aquaculture?
    Malachite Green and its primary metabolic derivative, Leucomalachite Green, are highly toxic and pose severe carcinogenicity and mutagenicity risks, including links to liver tumors in animal studies and long retention periods in aquatic tissues.
    What is the solubility profile of Basic Dye Malachite Green?
    It is soluble in water and highly soluble in ethanol, forming a vibrant blue-green solution. When mixed with sodium hydroxide, it forms a characteristic white precipitate displaying green fluorescence.
    How does Basic Green 4 perform under high temperature conditions?
    It exhibits excellent thermal stability with a stable shade up to 120°C and achieves high light fastness (grade 4–5) when applied to synthetic substrates such as acrylic and diacetate fibers.
    What safety precautions are recommended when handling this dye?
    Operators must wear suitable personal protective equipment (PPE) to prevent dust inhalation and skin/eye contact. Store the chemical in tightly sealed containers within a cool, dry, and well-ventilated storage facility.